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51.
Back Cover: New Polydentate Trimethylsilyl Chalcogenide Reagents for the Assembly of Polyferrocenyl Architectures (Chem. Eur. J. 23/2014) 下载免费PDF全文
52.
New Polydentate Trimethylsilyl Chalcogenide Reagents for the Assembly of Polyferrocenyl Architectures 下载免费PDF全文
Mahmood Azizpoor Fard Bahareh Khalili Najafabadi Mahdi Hesari Prof. Dr. Mark S. Workentin Prof. Dr. John F. Corrigan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(23):7037-7047
A series of polychalcogenotrimethylsilane complexes Ar(CH2ESiMe3)n, (Ar=aryl; E=S, Se; n=2, 3, and 4) can be prepared from the corresponding polyorganobromide and M[ESiMe3] (M=Na, Li). These represent the first examples of the incorporation of such a large number of reactive ?ESiMe3 moieties onto an organic molecular framework. They are shown to be convenient reagents for the preparation of the polyferrocenylseleno‐ and thioesters from ferrocenoyl chloride. The synthesis, structures, and spectroscopic properties of the new silyl chalcogen complexes 1,4‐(Me3SiECH2)2(C6Me4) (E=S, 1 ; E=Se, 2 ), 1,3,5‐(Me3SiECH2)3(C6Me3) (E=S, 3 ; E=Se, 4 ) and 1,2,4,5‐(Me3SiECH2)4(C6H2) (E=S, 5 ; E=Se, 6 ) and the polyferrocenyl chalcogenoesters [1,4‐{FcC(O)ECH2}2(C6Me4)] (E=S, 7 ; E=Se, 8 ), [1,3,5‐{FcC(O)ECH2}3(C6Me3)] (E=S, 9 ; E=Se, 10 ) and [1,2,4,5‐{FcC(O)ECH2}4(C6H2)] (E=S, 11 illustrated; E=Se, 12 ) are reported. The new polysilylated reagents and polyferrocenyl chalcogenoesters have been characterized by multinuclear NMR spectroscopy (1H, 13C, 77Se), electrospray ionization mass spectrometry and, for complexes 1 , 2 , 3 , 4 , 7 , 8 , and 11 , single‐crystal X‐ray diffraction. The cyclic voltammograms of complexes 7 – 11 are presented. 相似文献
53.
A simple, efficient, and ecofriendly procedure has been developed using propane-l,2,3-triyl tris(hydrogen sulfate) as a catalyst for the synthesis of biscoumarin derivatives in water and solvent-free conditions. The significant features of the present protocol are simplicity, environmentally benign, high yields, no chromatographic separation, and recyclability of the catalyst. 相似文献
54.
Hosseinikhah Seyed Mahdi Beigzadeh Borhan Siavashi Majid Halabian Mahdi 《Journal of Thermal Analysis and Calorimetry》2020,141(5):1543-1558
Journal of Thermal Analysis and Calorimetry - High interstitial fluid pressure in the tumor is among the most important barriers to drug delivery. The use of the static magnetic field is one of the... 相似文献
55.
Feng Li Melisa Rodas Ceballos Sepideh Keshan Balavandy Jingxi Fan Mohammad Mahdi Khataei Yadollah Yamini Fernando Maya 《Journal of separation science》2020,43(9-10):1854-1866
In the last 5 years, additive manufacturing (three‐dimensional printing) has emerged as a highly valuable technology to advance the field of analytical sample preparation. Three‐dimensional printing enabled the cost‐effective and rapid fabrication of devices for sample preparation, especially in flow‐based mode, opening new possibilities for the development of automated analytical methods. Recent advances involve membrane‐based three‐dimensional printed separation devices fabricated by print‐pause‐print and multi‐material three‐dimensional printing, or improved three‐dimensional printed holders for solid‐phase extraction containing sorbent bead packings, extraction disks, fibers, and magnetic particles. Other recent developments rely on the direct three‐dimensional printing of extraction sorbents, the functionalization of commercial three‐dimensional printable resins, or the coating of three‐dimensional printed devices with functional micro/nanomaterials. In addition, improved devices for liquid–liquid extraction such as extraction chambers, or phase separators are opening new possibilities for analytical method development combined with high‐performance liquid chromatography. The present review outlines the current state‐of‐the‐art of three‐dimensional printing in analytical sample preparation. 相似文献
56.
In this paper, the wave transmission from finite photonic crystals with multiple alternations is investigated using boundary element method (BEM). Since that, in these structures the alternation is not in all directions of space; the investigations of the frequency band gap with desired accuracy are not practical by analytical methods. Also, the frequency dispersion of dielectric rods is an effective parameter in photonic crystals, which this effect in our calculations has been considered. Due to the high capabilities of the BEM, the transmitted wave spectrum in the photonic crystal is calculated by changing the geometrical and optical parameters of the photonic crystal and applying more alternation in its structure and the position and width of the frequency band gap is investigated. Then, it is assumed that the photonic crystal with an arbitrary angle is rotated around the axis which is perpendicular on the crystal cross section and then, it is irradiated with a plan wave. The band gap of the photonic crystals with the desired structure, desired rotation angle and multiple alternations have been solved. Very low information volume, high speed and accuracy during the calculation and useable for any desired structures are the characteristics of this method. 相似文献
57.
Time-resolved 2H NMR spectroscopy is used to monitor the progress of and gain kinetic information for a variety of reactions in different ionic media. 相似文献
58.
Mahdi Sadeghi Zahra Alipoor Abbas Majdabadi 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(3):745-751
The 82Sr/82Rb radionuclide generator is used very commonly in positron emission tomography. ALICE/ASH and TALYS 1.0 codes were used to calculate excitation functions for proton, alpha and 3He induced on various targets that lead to produce 82Sr radioisotope using intermediate energy accelerators. Recommended thickness of the targets according to SRIM code was premeditated. The application of those data, particularly in the calculation of integral yields, is discussed and theoretical integral yields for any reaction were computed. To consider precision of TALYS 1.0 code calculations, 85Rb(p,4n)82Sr process was determined as most interesting one due to radionuclide purity. The TALYS 1.0 code predicts a maximum cross-section of about 130 mb at 47 MeV for this reaction. Rubidium chloride deposition on copper substrate was carried out via sedimentation method in order to produce 82Sr. 2.98 g RbCl, 1.043 g ethyl cellulose, 10 mL acetone were used to prepare a layer of enriched rubidium chloride of 11.69 cm2 area and 0.34 g/cm2 thickness. 相似文献
59.
A new finite volume (FV) approach with adaptive upwind convection is used to predict the two-dimensional unsteady flow in a square cavity. The fluid is air and natural convection is induced by differentially heated vertical walls. The formulation is made in terms of the vorticity and the integral velocity (induction) law. Biquadratic interpolation formulae are used to approximate the temperature and vorticity fields over the finite volumes, to which the conservation laws are applied in integral form. Image vorticity is used to enforce the zero-penetration condition at the cavity walls. Unsteady predictions are carried sufficiently forward in time to reach a steady state. Results are presented for a Prandtl number (Pr) of 0-71 and Rayleigh numbers equal to 103, 104 and 105. Both 11 × 11 and 21 × 21 meshes are used. The steady state predictions are compared with published results obtained using a finite difference (FD) scheme for the same values of Pr and Ra and the same meshes, as well as a numerical bench-mark solution. For the most part the FV predictions are closer to the bench-mark solution than are the FD predictions. 相似文献
60.
Y. G. Shee M. A. Mahdi M. H. Al-Mansoori A. Ismail N. A. M. A. Hambali A. K. Zamzuri R. Mohamad S. Yaakob 《Laser Physics》2009,19(12):2194-2196
A simple configuration for the reduction of stimulated Brillouin scattering threshold in photonic crystal fiber is presented.
The threshold reduction is contributed by the bidirectional pumping scheme through the reflection of transmitted Brillouin
pump back to the gain medium. The pump recycling scheme has greatly reduced the Brillouin threshold of a 200-m long of photonic
crystal fiber from 50 to 30 mW of Brillouin pump power. 相似文献